PRECIPITATIVE RE-EXTRACTION OF URANIUM(VI) FROM ORGANIC SOLUTIONS OF METHYLTRIOCTILAMMONIUM URANYL PEROXO-CARBONATE COMPLEXES
S.O. Frankiv, A.V. Boyarintsev, S.I. Stepanov
Pages: 78-83
DOI: 10.21175/RadProc.2021.15
Abstract |
References | Cite This | Full Text (PDF)
The article discusses the results of the uranium(VI)
re-extraction(stripping) from the methyltrioctilammonium organic phase
loaded by uranium(VI) peroxo-carbonate species using ammonium carbonate and
ammonium bicarbonate aqueous solutions or gaseous carbon dioxide.
Conditions for 97–99% re-extraction of uranium(VI) to obtain crystalline
ammonium uranyl carbonate with structure (NH4)4[UO 2(CO3)3] were determined.
-
S. I. Stepanov, A. M. Chekmarev, “Concept of spent nuclear fuel
reprocessing,” Dokl. Chem., vol. 423, no. 1, pp. 276–278, 2008.
DOI:
https://doi.org/10.1134/S0012500808110037
-
G. S. Goff et al., “Development of a novel alkaline based process for spent nuclear fuel recycling”, AIChE Annual Meeting, Nuclear Engineering Division, Salt Lake City (Utah), USA, Nov. 4–9, 2007.
-
N. Asanuma, M. Harada, Y. Ikeda, H. Tomiyasu, “New approach to the nuclear fuel reprocessing in non-acidic aqueous solutions,” J. Nucl. Sci. Technol., vol. 38, no. 10, pp. 866–871, 2001.
DOI:
https://doi.org/10.1080/18811248.2001.9715107
-
K. W. Kim et al., “Development of a treatment process and immobilization method for the volume reduction of uranium-bearing spent catalysts for final disposal,” J. Nucl. Sci. Tech., vol. 55, no. 12, pp. 1459–1472, 2018.
DOI:
https://doi.org/10.1080/00223131.2018.1516578
-
C. Z. Soderquist et al., “Dissolution of irradiated commercial UO2 fuels in ammonium carbonate and hydrogen peroxide,” Ind. Eng. Chem. Res., vol. 50, no. 4, pp. 1813–1818, 2011.
DOI:
https://doi.org/10.1021/ie101386n
-
С. И. Степанов, А. М. Чекмарёв, “Экстракция редких металлов солями четвертичных аммониевых оснований,” Москва, Россия: ИздАТ, 2004. (S. I. Stepanov, A. M. Chekmarev, Extraction of rare metals by the salts of quaternary ammonium bases, Moscow, Russia: IzdAT, 2004.)
-
V. Baran , F. Škvor, V. Voseček, “Formation of the ammonium-uranyl-carbonate complexes of the type (NH 4)4[UO2(CO3)3], prepared by precipitative re-extraction,” Inorg. Chim. Acta , vol. 81, pp. 83–89, 1984.
DOI:
https://doi.org/10.1016/S0020-1693(00)88739-3
- S. Chegrouche, A. Kebir, “Study of ammonium uranyl carbonate re-extraction-crystallization process
by ammonium carbonate,” Hydrometallurgy, vol. 28, no. 2, pp. 135–147, 1992.
DOI:
https://doi.org/10.1016/0304-386X(92)90126-K
-
Ю. А. Ревенко и др., “Способ переработки облученного ядерного топлива,”
патент RU2366012, Россия, Публ. 27.08.2009. (Yu. A. Revenko et al., “Method of irradiated nuclear fuel treatment,”
patent RU2366012, Russia, Publ. 08.27.2009.)
-
B. Yahi, A. Kebir, “Influence of process re-extraction-crystallization parameters on the
properties of ammonium uranyl-tricarbonate crystals,”
Hydrometallurgy, vol. 34, no. 1, pp. 65–78, 1993.
DOI:
https://doi.org/10.1016/0304-386X(93)90081-N
-
I. I. Chernyaev, Complex compounds of uranium, New York (NY), USA:
Daniel Davey & Co., Ink., 1966.
-
S. I. Stepanov et al., “CARBEX process, a new technology of reprocessing of
spent nuclear fuel,” Russ. J. Gen. Chem., vol. 81, no. 9,
pp. 1949–1959, 2011.
DOI:
https://doi.org/10.1134/S1070363211090404
-
S. I. Stepanov, A. V. Boyarincev, A. A. Chehlov, A. M. Chekmarev, A. Yu. Tsivadze, “Chemistry of the CARBEX process.
Identification of the absorption bands of the ligands in the electronic
spectra of U(VI) extracts with methyltrioctylammonium carbonate,” Dokl. Chem., vol. 473, no. 1, pp. 63–66, 2017.
DOI:
https://doi.org/10.1134/S0012500817030065
-
A. V. Boyarintsev et al., “Separation of uranium(VI) and americium(III) by extraction from Na2CO3-H2O2 solutions using methyltrioctylammonium carbonate in toluene,” Solvent Extr. Ion Exch., vol. 39, no. 7, pp. 745–763, 2021.
DOI:
https://doi.org/10.1080/07366299.2021.1876993
-
В. К. Марков, А. В. Виноградов, С. В. Елинсон, Уран, методы его определения, Москва, Россия: Атомиздат, 1960. (V. K. Markov, E. A. Vernyi, A. V. Vinogradov, Uranium, methods of its definition, Moscow, Russia: Atomizdat, 1960.)
-
Analytical Spectroscopy Library Volume 10: Separation, preconcentration, and spectrophotometry in inorganic analysis , Z. Marczenko, M. Balcerzak, Eds., 1st ed., New York (NY), USA: Elsevier Science, 2000.
-
Н. С. Тураев, И. И. Жерин, Химия и технология урана, Москва, Россия: ЦНИИАТОМИНФОРМ, 2005. (N. S. Turaev, I. I. Gerin, Chemistry and uranium technology, Moscow, Russia: TSNIYATOMINFORM, 2005.)
-
А. К. Бабко, В. С. Коденская, “Равновесия в растворе карбонатных комплексов
уранила,” ЖНХ, т. 5, но. 11, с. 2568–2574, 1960. (A. S. Babko, V. S. Kodenskaya, “Study of equilibria in a solution of uranyl carbonate complexes,” Russ. J. Inorg. Chem., vol. 5, no. 11, pp. 2568–2574, 1960.)
S.O. Frankiv, A.V. Boyarintsev, S.I. Stepanov, "Precipitative re-extraction of uranium(vi) from organic solutions of methyltrioctilammonium uranyl peroxo-carbonate complexes", RAD Conf. Proc, vol. 5, 2021, pp. 78-83, http://doi.org/10.21175/RadProc.2021.15
|